DIFFERENTIAL ENTHALPY OF HYDROGEN SULFIDE ADSORPTION IN ACTIVATED SORBENT FROM HYBRID TOMENTOSA TREE
Keywords:
adsorption, adsorbent, isotherm, relative pressure, enthalpy, microcalorimeter, hydrogen sulfide.Abstract
In the present article, the regularities of the adsorption differential enthalpy of hydrogen sulfide molecules on an activated carbon adsorbent obtained from the bark of the Paulownia tomentosa tree at a temperature of 303 K, depending on the adsorption value, as well as the mechanism of the sorption process, were investigated. From the stepwise change of the adsorption differential enthalpy of hydrogen sulfide molecules on the activated carbon adsorbent from the bark of the Paulownia tomentosa tree, it was determined that the number of active sites with respect to hydrogen sulfide is 0.25 mmol/g, and the formation of a pentamer complex of adsorbate/adsorbent in the ratio of 5H2S:adsorbent was established.
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Savrasova Yu.A., Bogdanovich N.I., Makarevich N.A., Beletskaya M.G. Carbon adsorbents based on lignocellulosic materials // Forestry magazine. - 2012. - №1. - рр.107-112.
Chugunov A.D., Filatova E.G. Adsorption of petroleum products by modified and activated adsorbents. // News of universities. Applied chemistry and biotechnology. – 2021. - №2 (11). - рр. 318-325.
Salimov I.R., Murodova Yu.M., Murodov M.N., Tilloev L.I., Khaitov R.R. Determination of the optimal mode for obtaining activated carbon from fruit seed shells for the purification of alkanolamines. // Universum: Technical sciences: electronic. scientific journal. - Moscow. - 2020. - №. -7 (76). - рр. 77-81.
P.Ya.Bachurin, V.A.Smirnov. Technology of vodka and liquor products. "Processing of vodka sorting with activated carbon" Physicochemical principles of processing with activated carbon. // NPP "Technofilter". - 2020. - рр. 5-13.
Kouznetsova T.F., Kopysh E.A., Kulbitskaya L.V., Jumaeva D.J., Ivanets A.I. Textural properties of ordered nanoporous silica synthesized on mesogenic template. // Proceedings of the National Academy of Sciences of Belarus, Chemical Series. -2023. -59(2). -рр.125–138.
Nistratov A.V., Skaryukin A.S., Klushin V.N. Production and study of the porous structure of mineral-carbon adsorbents based on silica gel and polymer waste. // Sorption and chromatographic processes. -2019. -Vol.19. -№2. -рр. 200-208
Kh.Bakhronov, O.Ergashev, Gʻ.Оchilov, N.Esonkulova, A.Ganiev, N.Akhmedova, O.Ochilova Study of isotherm, thermodynamic characteristics and sorption mechanism of toluene adsorption on zeolite CsZSM-5 by adsorption-calorimetric method // Edelweiss Applied Science and Technology. -2026. -vol. 8. №6. -рр. 6959-6966, https://doi.org/10.55214/25768484.v8i6.3508
O.Ergashev, Kh.Bakhronov, M.Asfandiyorov, M.Kokhkharov, A.Ganiev, N.Akhmedova, Sh.Tulyaganova, K.Nazirov, N.Esonkulova Isotherm and main thermodynamic characteristics of adsorption of carbonyl sulfide molecules on zeolite KA (MSS-558). // Edelweiss applied science and sechnology. -2025. -vol. 9. -№6. -pp. 287-301. https://doi.org/10.55214/25768484.v9i6.7795
Reymov A., Raxmatkarieva F., Koxxarov M., Bakhronov Kh., Isotherm of ammonia adsorption in zeolite CaA (M-34). // Science and Education in Karakalpakstan. -2024. -№3/2. -ISSN 2181-9203. -pp.257-262.
Kokhkharov M., Rakhmatkarieva F., Bakhronov Kh., Rakhmatullaeva M, Absalyamova I., Karimov Y. Differential entropy and thermokinetics of ammonia molecule adsorption on CaA zeolite (M-22). // E3S Web of Conferences. ICESTE 2024. -563. -01024.
Kokhkharov M., Rakhmatkarieva F., Bakhronov Kh., Akhmedova N., Rakhmatullaeva M., Karimov Y. Adsorption isotherm, differential heat, and sorption mechanism of ammonia on CaA zeolite //E3S WоC. Green Energy 2024. -587. -01017.