GIBS ENERGY OF HYDROGEN SULFIDE ADSORPTION INTO ACTIVATED SORBENT OBTAINED FROM PAULOWNIA-TOMENTOSA HYBRID WOOD
Keywords:
Hydrogen sulfide, аdsorption, adsorption microcalorimetry, activated carbon, Paulownia Tomentosa, Gibbs free energy.Abstract
For the first time, the fundamental energetic characteristics of hydrogen sulfide (H₂S) adsorption on an activated carbon sorbent derived from the wood of the hybrid form Paulownia tomentosa were determined using adsorption microcalorimetry. The differential values of Gibbs free energy were calculated. It was established that the concentration of active sites for hydrogen sulfide on the activated carbon adsorbent derived from the bark of Paulownia tomentosa is ~0.35 mmol/g. It was proven that, in general, hydrogen sulfide molecules form 4H₂S/adsorbent complexes on the activated carbon adsorbent derived from the bark of Paulownia tomentosa.
Downloads
References
Danish, M.; Ahmad, T. A review on utilization of wood biomass as a sustainable precursor for activated carbon production and application. Renewable & Sustainable Energy Reviews, 2018, 87, 1–21.
Jumayeva D.J., Raxmatullayeva N.T., Toirov O.Z, Numonov B.O., Shamuratova M.R. Obtaining of highly energy-efficient activated carbons based on wood. E3S Web of Conferences 410, 01018 (2023) (3).
Jumaeva D. J., Rakhmatullaeva N. T., Abdurakhimov A. A., Babaeva G. O. Study of the physicochemical characteristics of wood-based adsorbents. No. 4 (106), April 2023. DOI: 10.32743.
Jumaeva D. J., Rakhmatullaeva N. T., Shamuratova M. R., Abdurakhimov A. Kh., Ergashev O. K. Activation methods of Paulownia wood waste. Scientific Journal “Mechanics and Technology,” Namangan Institute of Engineering and Construction, No. 3(3), 2022.
Neme, I.; et al. Activated carbon from biomass precursors using phosphoric acid: A review. 2022.
Yang, Z.; et al. Lignin-based activated carbon using H₃PO₄ activation. Polymers, 2020, 12(12), 2829.
Murphy, O. P.; et al. A review on adsorption isotherms and design for water treatment. ACS Omega, 2023.
Choleva, E.; et al. Adsorption of hydrogen sulfide on activated carbon: mechanisms and practice. Processes, 2023.
Pet, I.; et al. Recent developments in the implementation of activated carbon in water treatment. Current Pollution Reports, 2024.
Bunker, B.; et al. Thermal regeneration of activated carbon used as an adsorbent. Sustainability, 2023, 15, 6435.
Vilén, A.; et al. Comparative life-cycle assessment of activated carbon production from various raw materials. Journal of Cleaner Production, 2022.
Luanwuthi, S.; et al. Techno-economic and environmental assessment of biomass-derived activated carbon. ACS Sustainable Chemistry & Engineering, 2024.
Nandi, R.; et al. Impact of KOH activation on biomass-derived porous carbon (высокие S_BET). ACS Omega, 2023.
Quintas Salamba, M.; et al. Porosity of activated carbon in water remediation. ACS ES&T Water, 2025.
Kh.Bakhronov, O.Ergashev, Gʻ.Оchilov, N.Esonkulova, A.Ganiev, N.Akhmedova, O.Ochilova Study of isotherm, thermodynamic characteristics and sorption mechanism of toluene adsorption on zeolite CsZSM-5 by adsorption-calorimetric method //Edelweiss Applied Science and Technology, 2026, vol. 8, №6, -PP. 6959-6966, https://doi.org/10.55214/25768484.v8i6.3508
O.Ergashev, Kh.Bakhronov, M.Asfandiyorov, M.Kokhkharov, A.Ganiev, N.Akhmedova, Sh.Tulyaganova, K.Nazirov, N.Esonkulova Isotherm and main thermodynamic characteristics of adsorption of carbonyl sulfide molecules on zeolite KA (MSS-558) //Edelweiss applied science and sechnology, 2025, vol. 9, №6, -pp. 287-301, https://doi.org/10.55214/25768484.v9i6.7795
Reymov A., Raxmatkarieva F., Koxxarov M., Bakhronov Kh., Isotherm of ammonia adsorption in zeolite CaA (M-34) //Science and Education in Karakalpakstan, 2024, №3/2, ISSN 2181-9203, pp.257-262.
Kokhkharov M., Rakhmatkarieva F., Bakhronov Kh., Rakhmatullaeva M, Absalyamova I., Karimov Y. Differential entropy and thermokinetics of ammonia molecule adsorption on CaA zeolite (M-22) //E3S Web of Conferences 563, 01024, ICESTE 2024.
Kokhkharov M., Rakhmatkarieva F., Bakhronov Kh., Akhmedova N., Rakhmatullaeva M., Karimov Y. Adsorption isotherm, differential heat, and sorption mechanism of ammonia on CaA zeolite //E3S Web of Conferences 587, 01017 Green Energy 2024.
Jumaeva D. J., Bakhonov KH. N., Sultanov A. U. Technology for obtaining sorption material based on Paulownia. Scientific and Technical Journal of Andijan Machine-Building Institute, Special Issue No. 1, 2024, pp. 252–259